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A variety of chalcedonic quartz that is distinguished by the presence of color banding in curved or irregular patterns (Fig. 1). Most agate used for ornamental purposes is composed of two or more tones or intensities of brownish-red, often…

A sodium-rich plagioclase feldspar mineral whose composition extends over the range Ab100An0 to Ab90An10, where Ab (= albite) is NaAlSi3O8 and An (= anorthite) is CaAl2Si2O8 (see illustration). Albite occurs in crustal igneous rocks as a major…

Most commonly, a generic name for all fossil resins, although it has been restricted by some to refer only to succinite, the mineralogical species of fossil resin that includes most of the Baltic Coast deposits. The time necessary to transform resin…

A lithium aluminum phosphate mineral of basic formula LiAl(PO4)(F). The structure of amblygonite consists of phosphate (PO4) groups of tetrahedra and AlO6 groups of octahedra. Each PO4 tetrahedron is connected to an AlO6 octahedron. Corner-sharing…

The transparent purple to violet variety of the mineral quartz. Although quartz is perhaps the commonest gem mineral known, amethyst (see illustration) is rare in the deep colors that characterize fine quality. Amethyst is usually colored unevenly…

A nesosilicate mineral, composition Al2SiO5, crystallizing in the orthorhombic system. Andalusite (Fig. 1) occurs commonly in large, nearly square prismatic crystals. The variety chiastolite has inclusions of dark-colored carbonaceous material…

A plagioclase feldspar with composition Ab70An30 to Ab50An50 (Ab = NaAlSi3O8; An = CaAl2Si2O8). Andesine (see illustration) occurs primarily in igneous rocks, often in a glassy matrix as small, chemically zoned, lathlike crystals known as…

A mineral with the chemical composition PbSO4. Anglesite occurs in white or gray, orthorhombic, tabular or prismatic crystals or compact masses (see illustration). It is a common secondary mineral, usually formed by the oxidation of galena. Fracture…

A mineral with the chemical composition CaSO4. Anhydrite (anhydrous calcium sulfate) occurs commonly in white and grayish granular masses, rarely in large, orthorhombic crystals (see illustration). Fracture is uneven and luster is pearly to…

The calcium-rich plagioclase feldspar with composition Ab0An100 to Ab10An90 (Ab = NaAlSi3O8; An = CaAl2Si2O8). Anorthite (see illustration) occurs in olivine-rich igneous rocks and rare volcanic ejecta (for example, at Mount Vesuvius, Italy, and…

The response of corals to environmental stress in which they eject the single-cell algae that live within the transparent coral tissue, making the white coral skeleton visible. Corals (Fig. 1) are animals that live in a partnership (symbiosis) with…

Marine animal life inhabiting the portion of the oceans below the upper limit of the continental slopes. The marine animals that make up the deep-sea fauna live below the photic zone of the oceans. In general, the deep sea may be regarded as that…

A rare mineral tectosilicate found in volcanic rocks high in potassium and low in silica. Kaliophilite is one of three polymorphic forms of KAlSiO4; the others are the rare mineral kalsilite and an orthorhombic phase formed artificially at about…

A theory expressing the idea that life on Earth passed through an era when biological processes were carried out predominantly by ribonucleic acids, without the involvement of deoxyribonucleic acids or proteins. The RNA World theory (or hypothesis)…

A chemical compound, (CH3)2CO; the first member of the homologous series of aliphatic ketones. Acetone (see illustration) is a colorless, volatile, and flammable liquid. Acetone occurs naturally in plants and animals. Its physical properties include…

In the Brönsted classification, an acid is any chemical species, ionic or molecular, capable of donating a proton (hydrogen ion) to another substance; the other substance acts as a base in accepting the proton. For these two interrelated classes of…

One of a large group of organic substances possessing the halocarbonyl group in which X stands for fluorine, chlorine, bromine, or iodine. The terms acyl and aroyl halides refer to aliphatic or aromatic derivatives, respectively.The great inherent…

A branch of meteorology that examines the effects and impacts of weather and climate on crops, rangeland, livestock, and various agricultural operations. Agricultural meteorology, or agrometeorology, addresses topics that often require an…

Natural and artificial substances in the atmosphere that affect human health or well-being, or the well-being of any other organisms in the environment. Air pollution also applies to situations in which contaminants affect structures and artifacts…

Any compound having highly basic properties, strong acrid taste, and ability to neutralize acids. Aqueous solutions of alkalies are high in hydroxyl ions, have a pH above 7, and turn litmus paper from red to blue. Caustic alkalies include sodium…

The elements of group 1 in the periodic table. Of the alkali metals, lithium differs most from the rest of the group, and tends to resemble the alkaline-earth metals (group 2 of the periodic table) in many ways. In this respect lithium behaves as do…

Usually calcium, strontium, and barium, the heaviest members of group 2 of the periodic table (excepting radium). Other members of the group are beryllium, magnesium, and radium, sometimes included among the alkaline-earth metals. Beryllium…

A nonsteroidal anti-inflammatory drug used to control pain, fever, and inflammation. Aspirin is one of the most prevalent medicines in the world and is used to reduce fever and treat minor aches, pains, and inflammation. Furthermore, it is the only…

An analytical technique for determining the composition of a sample in terms of the chemical elements present and their quantities or concentrations. Unlike other methods of elemental analysis, however, the sample is decomposed into its constituent…

A weapon that consists of integral rocket propulsion, means of pointing or guiding the weapon's velocity vector to a prescribed orientation at the position and time of rocket engine shutoff or burnout, and a warhead. In certain applications, means…

An organic acid, C6H5COOH; also known as benzene carboxylic acid. Benzoic acid is a crystalline solid, with the structure below. Benzoic acid has a melting point of 122°C, and sublimes at 100°C. Benzoic acid is only slightly soluble in water but is…

A chemical element, chemical symbol Be, atomic number 4, and atomic weight 9.0122. Beryllium is the first element in the group called alkaline-earth metals on the periodic table (Fig. 1). Alkaline-earth metals Atomic number Chemical element Periodic…

The study of the cycling of chemicals between organisms and the surface environment of the Earth. The chemicals either can be taken up by organisms and used for growth and synthesis of living matter or can be processed to obtain energy. The chemical…

In glass blowing, a long straight tube on which molten glass is gathered and worked, partly by blowing into the tube. The blowpipe (see illustration) is spun to shape the glass object further by centrifugal force, or by a tool, in which case the…

A chemical element, Cf, atomic number 98, the ninth member of the actinide series of elements. Its discovery and production have been based upon artificial nuclear transmutation of radioactive isotopes of lighter elements. All isotopes of…

Mercury(I) chloride, Hg2Cl2, a covalent compound which is insoluble in water. The substance sublimes when heated. The formula weight is 472.086 and the specific gravity is 7.16 at 20°C (68°F). The material is a white, impalpable powder consisting of…

A functional group found in organic compounds in which a carbon atom is doubly bonded to an oxygen atom. Depending upon the nature of the other groups attached to carbon, the most common compounds containing the carbonyl group are aldehydes (X…

A cluster compound containing both carbon (C) and boron (B) atoms as well as hydrogen (H) atoms external to the framework of the cluster. A cluster compound is one with insufficient electrons to allow for classical two-center two-electron bonds…

One of a large family of organic substances widely distributed in nature, and characterized by the presence of one or more carboxyl groups (COOH). These groups typically yield protons in aqueous solution.Acid and baseIn the type formula,…

Catenanes are compounds that are made of interlocking macrocycles. The interlocking rings are said to be mechanically rather than chemically bound. Catenanes are named according to the number of interlocking rings. The simplest catenane, containing…

A chemical element, Ce, atomic number 58, atomic weight 140.12. It is the most abundant metallic element of the rare-earth group in the periodic table. The naturally occurring element is made up of the isotopes 136Ce, 138Ce, 140Ce, and 142Ce. A…

A chemical element, Cs, with an atomic number of 55 and an atomic weight of 132.905, the heaviest of the alkali metals in group 1 of the periodic table (except for francium, the radioactive member of the alkali metal family). Cesium is a soft,…

System behavior that depends so sensitively on the system's precise initial conditions that it is, in effect, unpredictable and cannot be distinguished from a random process, even though it is deterministic in a mathematical sense. This article…

Charged particles can be accelerated to high velocities by electromagnetic fields. They are then able to travel through matter (termed an absorber), interacting with it, losing energy, and causing various effects important in many applications. In…

A branch of physical chemistry that seeks to explain time-dependent phenomena, such as energy transfer and chemical reaction, in terms of the detailed motion of the nuclei and electrons that constitute the system. As such, chemical dynamics seeks…

The study of ecological interactions mediated by chemicals that organisms produce. Chemical ecology seeks to integrate chemistry and biology in order to provide information about the chemical interactions among organisms and their environment (Fig.…

Atoms with the same atomic number; that is, the same number of protons in their atomic nucleus. Some common elements are oxygen, hydrogen, iron, copper, gold, silver, nitrogen, chlorine, and uranium (see illustration). Most of the elements are…

A useful but obsolescent term for the energy available from elements and compounds when they react, as in a combustion reaction. In precise terminology, there is no such thing as chemical energy, since all energy is stored in matter as either…

In a dynamic or kinetic sense, chemical equilibrium is a condition in which a chemical reaction is occurring at equal rates in its forward and reverse directions, so that the concentrations of the reactant and product substances do not change with…

A branch of physical chemistry that measures the rates of chemical reactions, describes them in terms of elementary steps, and understands them in terms of the fundamental interactions between molecules. Reaction kinetics Although the ultimate state…

A system of principles and rules used to name chemical compounds. Various nomenclature systems are used. Hence, a compound may have several acceptable names. Which name is preferred depends on the context. Each nomenclature type has several dialects…

A system of symbols and notation for the chemical elements and the combinations of these elements which form numerous chemical compounds. This system of symbols, devised since about 1800 by chemists, consists of letters, numerals, and marks that are…

The application of thermodynamic principles to systems involving physical and chemical transformations is carried out in order to (1) develop quantitative relationships among the identifiable forms of energy and their conjugate variables, (2)…

The type of luminescence wherein a chemical reaction supplies the energy responsible for the emission of light (ultraviolet, visible, or infrared) in excess of that of a blackbody (thermal radiation) at the same temperature and within the same…

A chemical discipline that uses mathematical and statistical methods to design or select optimal measurement procedures and experiments and to provide maximum chemical information by analyzing chemical data. Chemometrics is actually a collection of…