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A cycloaddition reaction between a diene and a dienophile. The simplest Diels-Alder reaction (O. Diels and K. Alder, 1928) occurs between butadiene and ethylene and is often referred to as a [4+2] cycloaddition. The numbers, four and two in…

Optical instruments that establish an optical line or axis for the purpose of aiming a weapon. The axis includes the observer's eye, a suitable mark in the instrument, and the target. For a pistol, the traditional iron sights employ a rear notch and…

Atmospheric ozone plays a critical role in the biosphere by absorbing harmful ultraviolet radiation in the stratosphere—the layer of the atmosphere about 10 to 50 km (6 to 30 mi) above Earth’s surface. Since the adoption of the Montreal Protocol in…

A solid or liquid (molten), opaque material with a lustrous surface and good electrical and thermal conductivities. Solid metal is usually crystalline and ductile and can be permanently deformed by shear on crystal planes (Fig. 1); permanent…

Weapons that arm warships. Of the wide variety of such weapons, three important categories are exclusively naval: antiship missiles, torpedoes, and mines. Other weapons all correspond to land-based types, but submarine-launched ballistic missiles…

Any of the compounds that bind one of the main members of the opioid receptor family (mu-, delta-, and kappa-opioid receptors). Opioid compounds, such as morphine (from the opium poppy), oxycodone, and fentanyl, are agonists (activators) at…

In physical chemistry, the various situations in which two or more phases (or states of aggregation) can coexist in thermodynamic equilibrium with each other, with the nature of the transitions between phases, and with the effects of temperature and…

A theory expressing the idea that life on Earth passed through an era when biological processes were carried out predominantly by ribonucleic acids, without the involvement of deoxyribonucleic acids or proteins. The RNA World theory (or hypothesis)…

A quantitative analysis technique for measuring the elemental composition of a sample. X-ray spectrometry (Fig. 1) differs from x-ray diffraction, whose purpose is the identification of crystalline compounds. It differs from spectrometry in the…

Cosmochemists have discovered the oldest solid material known to exist on Earth. The material, stardust, consists of silicon carbide grains measuring around one micrometer in size. The grains date back approximately 7 billion years, or about 2.5…