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A common medicine used to relieve mild to moderate pain and reduce fever. Acetaminophen (N-acetyl-p-aminophenol), or paracetamol, is a white crystalline compound with the molecular formula C8H9NO2 (Fig. 1). It is a member of the aniline family of…

A member of a group of organic compounds that can be considered as derived from ammonia by replacement of one or more hydrogens by organic functional groups. Generally amines are bases of widely varying strengths, but a few that are acidic are…

An analytical technique for determining the composition of a sample in terms of the chemical elements present and their quantities or concentrations. Unlike other methods of elemental analysis, however, the sample is decomposed into its constituent…

The ongoing lower level of species extinction intensity occurring between episodes of mass extinctions. Extinction is a normal part of the history of life. Out of every 100 species that have ever lived on Earth, 99 are no longer in existence.…

A poisonous colorless, odorless, tasteless gas (CO), resulting from the incomplete combustion of carbon-containing materials. Carbon monoxide (Fig. 1) is an indoor hazard causing hundreds of deaths annually, and it is one of the six major air…

The attractive force that holds atoms or ions together. Chemical bonds are very strong. To break one bond in each molecule in a mole of material typically requires an energy of many tens of kilocalories.It is convenient to classify chemical bonding…

A chemical element, Cl, atomic number 17 and atomic weight 35.453. Chlorine exists as a greenish-yellow gas at ordinary temperatures and pressures (see illustration). It is second in reactivity only to fluorine among the halogen elements, and hence…

Typically, an aquatic vertebrate with scales, gills, and paired fins. Fishes (Fig. 1) are found throughout the world's waterways, from saltwater oceans to freshwater streams and ponds. About 35,000 species of fishes have been described to date. Many…

In thermodynamics, the amount of useful work that can be extracted from a closed thermodynamic system. The Helmholtz free energy applies to a process that takes place at a constant temperature T (isothermal process). The Gibbs free energy applies to…

A space-traversing unmanned vehicle which contains the means for controlling its flight path and that delivers an explosive warhead with high accuracy. Various kinds of missiles are guided in the sense that they can aerodynamically adjust after…

A salt or ester of lactic acid (CH3CHOHCOOH). In lactates, the acidic hydrogen of the carboxyl group has been replaced by a metal or an organic radical. Lactates are optically active, with a chiral center at carbon 2. The two optical isomers of a…

An analytical technique for identification of chemical structures, determination of mixtures, and quantitative elemental analysis by measuring the mass-to-charge (m/z) ratio of ions produced when a sample is ionized. Determination of organic and…

A device that is capable of converting chemical energy into electrical energy with the use of whole bacterial cells as the catalyst. Fuels that are produced biologically are known as biofuels. Biofuel cells convert chemical energy from organic…

A chemical element, Os, atomic number 76, atomic weight 190.2. Osmium is a hard white metal of rare natural occurrence, and is usually found in nature alloyed with other platinum metals. Metal Periodic table Platinum The periodic table of the…

A two-component reaction involving the loss of electrons (oxidation) by one chemical species and the gain of electrons (reduction) by another; also known as a redox reaction. Both oxidation and reduction occur simultaneously and in equivalent…

The study of chemical changes resulting from the absorption of high-energy ionizing radiation. Such radiation includes alpha particles, electrons, gamma rays, fission fragments, protons, deuterons, helium nuclei, and heavier charged projectiles.…

A subdiscipline of paleobiology that investigates the processes of preservation and their influence on information in the fossil record. Taphonomy is the study of fossilization and considers the processes at work in the incorporation of living…

One of the elements of atomic numbers 21–31, 39–49, and 71–81. The symbols of these elements, along with their atomic numbers and valence-shell electronic configurations, are given in Fig. 1. The elements are arranged in the order in which they…

A chemical obtained from wood. Woody plants comprise the greatest part of the organic materials produced by photosynthesis on a renewable basis. Replacement of fossil hydrocarbons, from which most organic chemicals are derived, is possible in many…

The scattering of x-rays by matter with accompanying variation in intensity for specific directions (or wavelengths) due to interference effects. X-ray diffraction is a powerful and readily available method for determining atomic arrangements in…

Mechanized systems of food and fiber production used in agriculture. The mechanized systems comprising agricultural machinery are utilized in numerous aspects of agriculture, including the initial tillage of the soil (Fig. 1), planting, cultural…

A useful carbon-carbon bond-forming reaction in which aldehyde and alcohol functional groups are observed during the reaction. The aldol reaction was first reported by Aleksandr Porfiryevich Borodin, who observed the reaction using pentanal and…

A small, tropical, evergreen tree (Pimenta dioica) and its dried, unripe fruit (berry). Allspice (Pimenta dioica; alternatively, P. officinalis) [see illustration] is a member of the myrtle family (Myrtaceae). Allspice, which is also known as…

Most commonly, a generic name for all fossil resins, although it has been restricted by some to refer only to succinite, the mineralogical species of fossil resin that includes most of the Baltic Coast deposits. The time necessary to transform resin…

A genus of fossil birds in the extinct order Archaeopterygiformes, characterized by flight feathers like those of modern birds. Archaeopteryx is generally accepted as the oldest known fossil bird. It represents a unique snapshot of evolution; most…

Any vegetable that is prevalent in Asian cuisines, but less well known in Western diets. Asian vegetables (Fig. 1), also referred to as Asian greens or oriental vegetables, are very important in Asian countries, but are not as popular in North…

A chemical reaction or series of reactions leading to the predominant or exclusive formation of a single enantiomer, that is, one of an isomeric pair of chemical compounds whose molecules are nonsuperimposable mirror images. Enantiomers are said to…

An aromatic hydro­carbon, molecular formula C6H6, also know as benzol. Benzene is a clear, colorless, and flammable liquid which boils at 80.1°C and freezes at 5.5°C.Benzene (1) is an important chemical intermediate used to produce ethylbenzene…

An integrated device consisting of a biological recognition element and a transducer capable of detecting the biological reaction and converting it into a signal that can be processed. Ideally, the sensor should be self-contained, so that it is not…

The measurement of the quantity of heat transferred during chemical reactions, changes of state, mixing of substances, as well as other chemical and physical processes. The unit of energy in the International System of Units is the joule, symbolized…

A medium-sized, spreading evergreen tree (Anacardium occidentale), which is grown widely in the tropics for its kidney-shaped edible nuts (also called cashews) and the resinous oil in the shells of the nuts. Cashew trees, which are native to Brazil,…

A class in the phylum Mollusca that is exclusively marine and includes squids, octopuses, and cuttlefishes. The molluscan class Cephalopoda is one of the major taxonomic groupings of marine animals and contains both extant members—squids (Fig. 1),…

Any member of the grass family (Poaceae or Gramineae) that produces edible grains usable as food by humans and livestock. Cereals are important cultivated crops. Common cereals include rice, wheat, barley, oats, maize (corn), sorghum, rye, and…

An order of the class Reptilia, including the turtles, terrapins, and tortoises; also termed Testudines. The order Chelonia (often referred to as Testudines) comprises one of the oldest groups of reptiles on Earth. Members of the Chelonia…

A branch of physical chemistry that seeks to explain time-dependent phenomena, such as energy transfer and chemical reaction, in terms of the detailed motion of the nuclei and electrons that constitute the system. As such, chemical dynamics seeks…

A white or colorless amorphous polysaccharide that forms a base for the hard outer integuments of crustaceans, insects, and other invertebrates. Chitin (see illustration) is an important nitrogenous polysaccharide that is found abundantly in nature.…

An evergreen shrub or small tree, particularly Cinnamomum verum, and the spice obtained from the plant's bark. The cinnamon plant (see illustration) is a member of the laurel family (Lauraceae) in the order Laurales. Native to Sri Lanka, the…

Any living or fossil member of the plant division Pinophyta, consisting chiefly of woody trees or shrubs that produce cones and evergreen needles. Conifers are predominantly cone-bearing, evergreen trees and shrubs belonging to the order Pinales, as…

A cycloaddition reaction between a diene and a dienophile. The simplest Diels-Alder reaction (O. Diels and K. Alder, 1928) occurs between butadiene and ethylene and is often referred to as a [4+2] cycloaddition. The numbers, four and two in…

The transport of matter from one point to another by random molecular motions. Diffusion occurs in gases, liquids, and solids.Diffusion plays a key role in processes as diverse as permeation through membranes, evaporation of liquids, dyeing textile…

A system that delivers controlled amounts of a therapeutic agent over a prolonged period or in a desirable temporal fashion, thereby maintaining required plasma or tissue drug levels. Drug delivery systems are bioengineered mechanisms or devices…

A volatile, fragrant oil obtained from plants. Essential oils are distinguished from those known as fixed oils, which are mainly triglycerides of fatty acids. Essential oils have been obtained from thousands of plants (Fig. 1) and are designated and…

The simplest cyclic ether or epoxide, with the formula C2H4O. Ethylene oxide is also called epoxyethane and oxirane, and has the below structure. Ethylene oxide was discovered in 1859 by C. A. Wurtz. His preparation from ethylene chlorohydrin and…

The death and disappearance of a species. The extinction of a species usually represents an end point in a long series of population extinctions. During the extinction process, unique evolutionary history is lost at every stage, but the death of the…

A method of separating the constituents of a mixture using preferential solubility of one or more components in a second phase. Commonly, this added phase is a liquid, while the mixture to be separated may be either solid or liquid. For example, the…

An enzymatic transformation of organic substrates, especially carbohydrates, generally accompanied by the evolution of a gas. Fermentation is a chemical transformation of organic substrates, especially carbohydrates, to alcohol or organic acids,…

The application of different types of energy and techniques involving equipment and apparatuses to transform agricultural products of plant and animal origin or seafood into food ingredients, semifinished commodities, and finished ready-to-eat…

The study of the physical, chemical, and biological properties of foods as well as the sensory, nutritional, storage properties, and safety of foods. Food properties are influenced by growing, harvesting, and slaughtering practices, preservation and…

Any of the grasses and legumes that make up grasslands and are consumed by grazing livestock. Grasslands represent an ancient renewable natural resource. In general, grasslands form 25% of the world's vegetation and occupy the largest area of any…

A record of earlier life buried in rock. Originally meaning any distinctive object that has been dug up (from Latin fodio, dig), the term “fossil” soon came to refer particularly to things resembling animals and plants. These objects were known…

A hardy perennial, Allium sativum, of Asiatic origin and belonging to the plant order Asparagales. Garlic is grown for its pungent bulbs (see illustration). Segments of these are used primarily for seasoning. Europeans have grown garlic for probably…

Qualitative identifications and quantitative determinations of substances essential for the evaluation of the air quality in the ambient air and in the industrial workplace.The terms air pollution and gas analysis are used here in the broad sense.…

An important spice or condiment, and the plant (Zingiber officinale) from which it is obtained. The ginger plant, Zingiber officinale, is a member of the ginger family Zingiberaceae and is a native of southeastern Asia. The plant is an erect…

Any of the crop plants belonging to the grass family (Poaceae or Gra­mineae) that are generally grown for their edible starchy seeds. Grain crops are often referred to as cereal crops and include wheat, rice, corn (maize), barley (see illustration),…

The discovery, development, and application of sustainable chemical reactions that create no waste or generate only benign wastes. The idea that toxic chemicals, once created, can be contained or prevented from entering the environment is…

Optical instruments that establish an optical line or axis for the purpose of aiming a weapon. The axis includes the observer's eye, a suitable mark in the instrument, and the target. For a pistol, the traditional iron sights employ a rear notch and…

An aliphatic or aromatic hydrocarbon in which one or more hydrogen atoms are substituted by halogen atoms. Alkyl halides Alkyl halides are compounds in which one hydrogen of an alkane has been replaced by halogen [fluorine (F), chlorine (Cl),…

An intensively managed plant cultivated for food or for esthetic purposes. Plant agriculture is divided traditionally into the fields of agronomy (herbaceous field crops, mainly grains, forages, oilseeds, and fiber crops), forestry (forest trees and…

A chemical element, Fe, atomic number 26, and atomic weight 55.845. Iron is a malleable, tough, silver-gray, magnetic metal. It melts at 1540°C, boils at 2800°C, and has a density of 7.86 g/cm3. The four stable, naturally occurring isotopes have…

Intentional generation of interfering signals in the electromagnetic spectrum by powerful transmitters as a countermeasure intended to block a communication, radar, or infrared system or to impair its effectiveness appreciably. Radio broadcasts or…

The common name for a member of the agnathan fishes. The fish superclass Agnatha (subphylum Vertebrata, phylum Chordata) comprises the jawless vertebrates (agnathans). Members include cyclostomes (modern lampreys and hagfishes), various extinct…

Solvent removal from the frozen state by sublimation; commonly referred to as freeze-drying. In lyophilization, the dried material, a porous solid, is sealed under vacuum or inert-gas (liquid nitrogen) atmosphere and retains its physical and…

A lineage of true elephants in the extinct genus Mammuthus that occupied Eurasia and North America in the late Cenozoic Era. Mammoths (genus Mammuthus) are extinct elephants assigned to the mammalian order Proboscidea (Fig. 1). They inhabited…

The widespread, catastrophic loss of many species in a relatively short period of geological time. Earth has supported life for approximately 3.5 billion years, and it is normal for species to become extinct and for new species to arise through…

A solid or liquid (molten), opaque material with a lustrous surface and good electrical and thermal conductivities. Solid metal is usually crystalline and ductile and can be permanently deformed by shear on crystal planes (Fig. 1); permanent…

A type of protein that shuttles metal ions to specific sites within a cell. Metallochaperones are molecular facilitators that transport metal ions to target proteins (see illustration). The target sites for metal delivery include a number of…

The smallest unit of a compound, which consists of atoms bonded together in a unique arrangement. A diatomic molecule consists of two atoms linked together by chemical bonds. Examples include the oxygen and nitrogen of the air (O2 and N2,…

A major phylum of the animal kingdom comprising a diverse group of unsegmented, soft-bodied invertebrates. The phylum Mollusca is one of the most significant groupings of invertebrate animals. Members of the Mollusca, termed mollusks or molluscs,…

A mammalian order containing the egg-laying platypus and echidnas. Members of the order Monotremata (monotremes) are egg-laying mammals belonging to the subclass Prototheria (in some alternative classifications, the monotremes have been assigned to…

Weapons that arm warships. Of the wide variety of such weapons, three important categories are exclusively naval: antiship missiles, torpedoes, and mines. Other weapons all correspond to land-based types, but submarine-launched ballistic missiles…

A class of chemicals characterized by their common chemical structure and potentially fatal nervous system effects. Development and historical use Research into organophosphate insecticides led to the development of nerve agents in the 1930s. Nerve…

The process of turning free nitrogen gas (N2) into chemical compounds, usually ammonia (NH3), which can be used by growing plants as a source of nitrogen. Gaseous N2 makes up the majority of the atmosphere, but higher organisms cannot use it because…

The Nobel Prizes for 2021 included the following awards for scientific disciplines. Chemistry The chemistry prize was awarded jointly to Benjamin List of the Max-Planck-Institut für Kohlenforschung, Mülheim an der Ruhr, Germany, and David W.C.…

The cultivation of plants, primarily trees, that produce nuts. The term nut is used loosely. In general, a nut is defined as any edible fruit or seed enclosed in a hard shell. Botanically, a nut is a hard, indehiscent, one-seeded (nut), pericarp…

A delicately flavored spice obtained from the nutmeg tree (Myristica fragrans), a native of the Moluccas (Maluku Islands or Spice Islands). The nutmeg tree is a dark-leafed evergreen that can reach 9–18 m (30–60 ft) in height and is a member of the…

A small extinct order of articulated brachiopods that ranges in age from Early to Middle Cambrian and includes the earliest known calcitic brachiopods. Classification The order Obolellida is included within the class Obolellata, subphylum…

An order of coleoid cephalopods, characterized by eight appendages (which encircle the mouth), a saclike body, and an internal shell that is much modified or reduced from that of its ancestors. Members of the order Octopoda (subclass Coleoidea,…

A morphologically distinct type of trace fossil left by boring organisms in hard biogenic substrates. Oichnus Bromley 1981 is a formal taxonomic name with the rank of ichnogenus (a trace fossil genus). Oichnus is a Latin-derived term that…

A suborder of trilobites (a class of extinct arthropods) and a diverse clade consisting of roughly 100 distinct species. The trilobites constituting the suborder Olenellina belong to the order Redlichiida in the class Trilobita. These extinct…

Any plant of the genus Olea in the order Lamiales (alternatively Scrophulariales), especially O. europaea, which is cultivated for its drupaceous fruit. Olea europaea is a small to medium-sized evergreen tree (Fig. 1). Olive fruits, both ripe…

A class of the subphylum Asterozoa (phylum Echinodermata), comprising the brittle stars and basket stars, in which the arms are usually clearly demarcated from a central disk and perform whiplike locomotor movements, and the tube feet are…

Any synthetic or semisynthetic organic chemical compound that resembles opium in its pharmacological action to reduce pain. An opioid is an organic chemical compound, created synthetically or semisynthetically, that duplicates the analgesic…

The use of organic molecules to catalyze chemical reactions. The catalytic activity of nitrogen-containing aliphatic and heterocyclic organic compounds has been exploited since the early days of chemistry, for example, in acylation reactions,…

A chemical reaction in which some composition variable of a chemical system exhibits regular periodic variations in time or space. It is a basic tenet of chemistry that a closed system moves inexorably toward an unchanging state called chemical…

A taxonomic fish group comprising the bony fishes. The Osteichthyes grouping (often considered a superclass) consists of the classes Actinopterygii (ray-finned fishes) and Sarcopterygii (lungfishes and lobefins, or coelacanths, but excluding…

Fossil lobe-finned (sarcopterygian) fishes of Devonian to Permian age (395–270 million years ago), the ancestral group for the land vertebrates, or “tetrapods.” Phylogeny The term “osteolepiforms” is applied to a range of fossil fishes, found…

An order of extinct jawless vertebrate fishes, also called Cephalaspida, known from the Middle Silurian to Upper Devonian of Europe, Asia, and North America. They were mostly small, about 2 in. (5 cm) to 2 ft (60 cm) in length. The head and part of…

A major taxon of the Crustacea containing small bivalved animals 0.004–1.4 in. (0.1–33 mm) long, with most between 0.04 and 0.08 in. (1 and 2 mm). Members of the Ostracoda inhabit aquatic environments in nearly all parts of the world.…

A popular name applied to several groups of extinct jawless vertebrates (fishes). Most ostracoderms were covered with an external skeleton or armor of bone, from which is derived their name, meaning “shell-skinned” (see illustration). They are known…

A gaseous chemical element, O, atomic number 8, and atomic weight 15.9994. Oxygen is in the first row of the group 16 elements on the periodic table (Fig. 1), known as the chalcogens or the oxygen family. Oxygen is of great interest because it is…

A peculiar arthropod, evidently related to the Pycnogonida and represented by a number of well-preserved fossils from the Devonian Hunsrück shales. Palaeoisopus was formerly considered by a number of paleontologists to have an anterior jointed…

A large, extinct assemblage of primitive ray-finned (actinopterygian) fishes known from the Silurian to Cretaceous, which were most numerous in Carboniferous and Permian times. They are known as fossils from all continents except Antarctica.…

A tiny fossil fish found only in rocks of Middle Devonian age within a small geographic region of Caithness, Scotland, and principally at one site, Achanarras Quarry, where it is surprisingly abundant. One of the most enigmatic of all fossil fishes,…

The study of chemical processes used by organisms that lived in the geological past. Most information on the nature of life in the geological past comes from the study of fossils; a record of biochemical processes that occurred can be found in the…

The study of pollen grains and spores, both extant and extinct, as well as other organic microfossils. Although the origin of the discipline dates back to the seventeenth century, when modern pollen was first examined microscopically, the term…

A fossil lobe-finned (sarcopterygian) fish from rock strata of the Baltic region dating to the Middle–Late Devonian Period (about 372–368 million years ago), which provides key evidence about the evolutionary transition from fish to land vertebrates…

An extinct order of relatively large placental mammals represented by Paleocene-Eocene fossils from western Europe, North America, and eastern Asia. Pantodonts were an early evolutionary experiment in large-bodied herbivory by primitive placental…

A type of pepper, Capsicum annuum, with nonpungent flesh, grown for its long red fruit. The paprika pepper (see illustration) is a member of the plant order Solanales (formerly assigned to Polemoniales) and is of American origin. It is most popular…

A medium-sized class of extinct blastozoan echinoderms containing about 17–19 genera, ranging from the late Early Ordovician to the Early Silurian throughout North America and in northern Europe. Their maximum standing diversity (13 genera) occurred…

The mint species Mentha piperita in the family Lamiaceae (Labiatae). Peppermint (see illustration) is a sterile interspecific hybrid that is believed to have occurred in nature from the hybridization of fertile Mentha aquatica with fertile Mentha…