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from article Bioorganic chemistry
Foldamers that mimic proteins.
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from article Bioorganic chemistry
The rate of this intramolecular lactonization, relative to that of intermolecular esterification, mimics the rate increase caused by an enzyme's binding and orienting substrates for a bimolecular reaction.
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from article Bioorganic chemistry
Intramolecular models of enzymatic general acid and general base catalysis. (a) Intramolecular general acid catalysis causes this acetal to hydrolyze at pH 7 more than 107 times faster than the corresponding acetal without the carboxylic acid group.…
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from article Bioorganic chemistry
An antibody raised against the phosphonate analog of a tetrahedral intermediate catalyzes the hydrolysis of cocaine to ecgonine methyl ester.
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from article Bioorganic chemistry
A functionalized cyclodextrin mimics the enzyme RNase by catalyzing the regioselective hydrolysis of a model phosphodiester.
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from article Bioorganic chemistry
Enzyme-catalyzed reactions that have been commercialized as industrial processes.
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from article Bioorganic chemistry
Mechanism of DNA scission by calicheamicin. Reductive or nucleophilic cleavage of the trisulfide triggers conjugate (Michael) addition to the enone, rehybridization of the bridgehead carbon, and Bergman cyclization of the enediyne, generating a…
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from article Negative temperature
Populations (n) of states of a thermodynamic system consisting of N magnetically interacting nuclei of spin 2 at absolute temperatures T = +D/k and T = −D/k, where k is Boltzmann's constant and D is the energy spacing between successive states.
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from article Type 1 diabetes
One characteristic feature of type 1 diabetes is glomerulosclerosis (Kimmelstiel-Wilson lesion), which involves the scarring or hardening of the glomeruli (blood vessels) in the kidneys. (Copyright © McGraw-Hill Education)
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from article Type 1 diabetes
Stages in the development of type 1 diabetes. (Credit: Type 1 Diabetes TrialNet)
