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Dai, Chunhui Department of Chemistry, Boston University, Boston, Massachusetts.
Stephenson, Corey R.J. Department of Chemistry, University of Michigan, Ann Arbor, Michigan.
- General information of Ru(bpy)32+
- Synthetic applications of Ru(bpy)32+ employing the reductive quenching pathway
- Synthetic applications of Ru(bpy)32+ employing the oxidative quenching pathway
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A century ago, Giacomo Ciamician, a pioneer of modern photochemistry, envisioned a future where solar energy could be converted and stored through artificial photosynthetic processes, providing a clean alternative to fossil fuels. Subsequently, natural sunlight has been recognized as a free and sustained energy resource with its use holding the potential for tremendous environmental benefits. Numerous attempts have been made by the chemical community to design suitable photosynthetic systems that mimic natural photofunctional organisms. However, the inability of many organic molecules to absorb sunlight in the visible range of the spectrum has severely impeded the development of visible-light photochemistry.
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